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The primary battery converts chemical energy to electrical energy directly, using the chemical materials within the cell to start the action.

The secondary battery must first be charged with electrical energy before it can convert chemical energy to electrical energy.

The secondary battery is frequently called a storage battery, since it stores the energy that is supplied to it.


 

Lead Acid Battery

  • Electrolyte for the most part distilled (pure) water, with some sulfuric acid mixed with the water.

  • Electrodes must be of dissimilar metals.

  • An active electrolyte.

 

 

 


Cells

  • Positive electrode

  • Negative electrode

  • Electrolyte

  • Separator


The basic primary wet cell

  • The metals in a cell are called the electrodes, and the chemical solution is called the electrolyte.

  • The electrolyte reacts oppositely with the two different electrodes

  • It causes one electrode to lose electrons and develop a positive charge; and it causes one other electrode to build a surplus of electrons and develop a negative charge.

  • The difference in potential between the two electrode charges is the cell voltage.

 


The Electrolyte

  • When charging first started, electrolysis broke down each water molecule (H2O) into two hydrogen ions (H+) and one oxygen ion (O-2).

  • The positive hydrogen ions attracted negative sulfate ions (SO4-2) from each electrode.

  • These combinations produce H2SO4, which is sulfuric acid.

Electrolysis

  • The producing of chemical changes by passage of an electric current through an electrolyte.


Specific Gravity

  • Ratio of the weight of a given volume of a substance to the weight of an equal volume of some reference substance, or, equivalently, the ratio of the masses of equal volumes of...

  • Example: It is the weight of the sulfuric acid - water mixture compared to an equal volume of water. Pure water has a specific gravity of 1,000.
     


Hydrometer: Device used to determine directly the specific gravity of a liquid.

The chart below gives state of charge vs. specific gravity of the electrolyte.

State of Charge

100% Charged
75% Charged
50% Charged
25% Charged
Fully Discharged

Specific Gravity

1.265
1.239
1.200
1.170
1.110

                These readings are correct at 75°F

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